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When I need to discussion to some one about the problem in a detailed way, It seems better to do it in a chat-room instead of comments. But what is the usual way to do this.(I do this once some weeks ago in TeX.StackExchange.com but it was automatically and I want to do this manually.)

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You can't move comments from the main site to chat if the automatic mechanism is not triggered, not even moderators can do that.

You can open a new chat room and invite the other user into it, either use the "invite to room" feature in chat or add another comment with a link to the chat room you created. You could also manually copy the comments into chat.

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